Checking current values
There is no separate current-values screen. Running a comparison is how you read the current configuration of your servers: Compare queries each server live and reports what it finds.
To see every value rather than only the differences, run Compare as normal, then set the row filter to All rows. This shows every value Compare collected for the ticked servers and comparisons, whether or not it differs between them.
If you want a record of a server's configuration to keep or compare against later, take a snapshot instead of, or as well as, running a live comparison.